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Kinetic studies on the electron transfer between sulphur(IV) and an iron(III) oxime–imine complex

✍ Scribed by Mahammad Ali; Basudeb Saha


Book ID
110407973
Publisher
Springer
Year
2002
Tongue
English
Weight
98 KB
Volume
27
Category
Article
ISSN
0340-4285

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The iron(II) complex of H 2 L 14-dimethyl-4, 7, 10, 13-tetraazahexadeca-(H L ϭ 3, 2 3,13-diene-2,15-dione dioxime, Coord. Chem. Rev., 33, 87 (1980)) is oxidized by periodate very rapidly in the range pH 2.0-7.0, and the kinetics of the reaction has been followed by stoppedflow spectrophotometry at 3