Electron transfer from thiosulfate to nickel(IV) oxime imine complexes in aqueous solution
β Scribed by Bhattacharya, Santanu; Ali, Mahammad; Gangopadhyay, Sumana; Banerjee, Pradyot
- Book ID
- 115463909
- Publisher
- The Royal Society of Chemistry
- Year
- 1996
- Tongue
- English
- Weight
- 813 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1472-7773
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The kinetics of electron transfer from phenylhydrazine(S) to tris-(dimethylglyoximato) nickelate(IV), Ni(dmg)i-(dmg2-= dimethylglyoximate dianion), have been studied in aqueous medium in the range of 6.21 I pH I 12.2. The kinetics exhibit a pseudo-first-order disappearance of Ni(dmg)g-when excess S
The kinetics of decomposition of "oxohydroxonickel(1V)" [Ni(IV)] with concomitant intramolecular electron transfer to produce hexaaquanickel(I1) and dioxygen in aqueous acid solutions show pseudo-first-order disappearance of the Ni(IV). The pseudo-first-order rate constants for the acid decompositio