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Electron transfer from thiosulfate to nickel(IV) oxime imine complexes in aqueous solution

✍ Scribed by Bhattacharya, Santanu; Ali, Mahammad; Gangopadhyay, Sumana; Banerjee, Pradyot


Book ID
115463909
Publisher
The Royal Society of Chemistry
Year
1996
Tongue
English
Weight
813 KB
Volume
13
Category
Article
ISSN
1472-7773

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The kinetics of electron transfer from phenylhydrazine(S) to tris-(dimethylglyoximato) nickelate(IV), Ni(dmg)i-(dmg2-= dimethylglyoximate dianion), have been studied in aqueous medium in the range of 6.21 I pH I 12.2. The kinetics exhibit a pseudo-first-order disappearance of Ni(dmg)g-when excess S

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The kinetics of decomposition of "oxohydroxonickel(1V)" [Ni(IV)] with concomitant intramolecular electron transfer to produce hexaaquanickel(I1) and dioxygen in aqueous acid solutions show pseudo-first-order disappearance of the Ni(IV). The pseudo-first-order rate constants for the acid decompositio