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Kinetics and mechanism of the oxidation of hydroxylamine by a {Mn3O4}4+ core in aqueous acidic media

✍ Scribed by Chandra Mandal, Pulak; Chakraborty, Maharudra; Das, Suranjana; Estarellas, Carolina; Quiñonero, David; Frontera, Antonio; Mukhopadhyay, Subrata

Book ID
126776751
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
855 KB
Volume
40
Category
Article
ISSN
1477-9226

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## Abstract In aqueous media, the Mn^IV^ trimer [Mn^IV^~3~(μ‐O)~4~(phen)~4~(H~2~O)~2~]^4+^ (1, phen = 1,10‐phenanthroline) equilibrates with its deprotonated from [Mn~3~(μ‐O)~4~(phen)~4~(H~2~O)(OH)]^3+^ (2). Among the several synthetic multinuclear oxo‐ and/or carboxylato‐bridged manganese complexe

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