The ratio r = [lICl]/[ DCI], for the decomposition of ethyl Wt chloride, CH2DCII2CI, induced by mtcn\c CO2 h\cr ~UIIIS, has been mummd under dlffcrcnt cxperimcntal condition\. Changes in be;ml cncrgy, bc;mr peomctry. rohtlon,ll he% irradiatton tanc and pressure have no discernible cffcct 01' r. It i
Isotopic dilution effect on the IR absorption bandshape of CH2Cl2
β Scribed by P.C.M. Van Woerkom; J. De Bleyser; J.C. Leyte
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 232 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The shape of the 1265 cix@ absorption btind in liquid C&C12 ch;u?ges on dilution with &e deuterated compound. This is discussed in terms of intermdeculv vibrational refaxxtior. The important influexe of molecular reorientaliox on ~ribrational relaxation is pointed out.
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