✦ LIBER ✦

Additive effect of CF3Cl on OH∗, CH∗, and C2∗ emissions: Shock tube study with C2H4O2CF3Cl and CH4O2CF3Cl mixtures

✍ Scribed by Yoshiaki Hidaka; Masao Suga

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 373 KB
Volume: 60
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(85)90028-8

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A kinetic study of the reaction of fluor

A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K

✍ Timothy J. Wallington; Michael D. Hurley; Jichun Shi; M. Matti Maricq; Jens Sehe 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 807 KB

A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.

A kinetic study of the reaction of chlor

A kinetic study of the reaction of chlorine atoms with CF3CHCl2, CF3CH2F, CFCl2CH3, CF2ClCH3, CHF2CH3, CH3D, CH2D2, CHD3, CD4, and CD3Cl at 295±2 K

✍ T.J. Wallington; M.D. Hurley 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 484 KB

Theoretical study of the reactions CF3CH

Theoretical study of the reactions CF3CH2OCHF2 + OH/Cl and its product radicals and parent ether(CH3CH2OCH3) with OH

✍ Lei Yang; Jing-Yao Liu; Li Wang; Hong-Qing He; Ying Wang; Ze-Sheng Li 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 603 KB

## Abstract A dual‐level direct dynamic method is employed to study the reaction mechanisms of CF~3~CH~2~OCHF~2~ (HFE‐245fa2; HFE‐245mf) with the OH radicals and Cl atoms. Two hydrogen abstraction channels and two displacement processes are found for each reaction. For further study, the reaction m

ChemInform Abstract: New or Improved Syn

ChemInform Abstract: New or Improved Syntheses of the Polyfluoroalcohols HOC(cyclo-C6H11)2(CF3), HO(cyclo-C6H11)(CF3)2, and HOC(Ar)(CF3)2 (Ar = 4-C6H4(tBu), 2,4,6-C6H2(CF3)3, 4-Si(iPr)3-2,6-C6H2 (CF3)2, 3,5-C6H3(CH3)2), and 2-C6H4(C(OH)(CF3)2).

✍ Thomas J. Barbarich; Benjamin G. Nolan; Shoichi Tsujioka; Susie M. Miller; Oren 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 3 views

UV absorption spectra of HO2, CH3O2, C2H

UV absorption spectra of HO2, CH3O2, C2H5O2, and CH3C(O)CH2O2 radicals and mechanism of the reactions of F and Cl atoms with CH3C(O)CH3

✍ Ole J. Nielsen; Matthew S. Johnson; Timothy J. Wallington; Lene K. Christensen; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB

## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0

Reactions of Cl2P3/2: Absolute rate cons

Reactions of Cl2P3/2: Absolute rate constants for reaction with H2, CH4, C2H6, CH2Cl2, C2Cl4, and cC6H12

✍ D. D. Davis; W. Braun; A. M. Bass 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 863 KB

The absolute rate constants have been measured for several gas-phase chlorine atommolecule reactions a t 25OC by resonance fluorescence. These reactions and their corre- sponding rate constants in units of cm3 mole-' sec-l are: The effects of varying the substrate pressure, total pressure, light in