✦ LIBER ✦

Intramolecular isotope effect in laser multiphoton dissociation of CH2DCH2Cl

✍ Scribed by A.J. Colussi; S.W. Benson; R.J. Hwang; J.J. Tiee

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 488 KB
Volume: 52
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80557-5

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✦ Synopsis

The ratio r = [lICl]/[ DCI], for the decomposition of ethyl Wt chloride, CH2DCII2CI, induced by mtcn\c CO2 h\cr ~UIIIS, has been mummd under dlffcrcnt cxperimcntal condition. Changes in be;ml cncrgy, bc;mr peomctry. rohtlon,ll he% irradiatton tanc and pressure have no discernible cffcct 01' r. It is hewn tht .I nxrow distributmn with an avcrapc excess energy of I:'; = 15 5 2 photons (35-46 kcal/tuolc) and KRKM theory arc mutually consiFtcnt w1t11 the ohcrvcd value of r = 2.6 f 0.1. 'll~ implications of these results for the mcchamsm of multiphoton ab\orptlon are analyxd.

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