The dwowuon of STsCI and CFS1 scnslttzed by multIphoton cwtation of SF6 by a pulsed CO1 Iascr has been studxd vrrsus prcssurc. laser lluence, mert gasend oplical frcqucncy. lsoto P \_ IC cfrccls have been obscrvcd bclwccn 3zST~Cl/37S~~CI and bcrwccn '3Cr#\*Cr31 and selccriv~ty factors as tngh as (r&
Effects of wavelength, pressure and scavengers on the isotopically selective multiphoton dissociation of C2F5Cl
✍ Scribed by E. Borsella; R. Fantoni; A. Giardini-Guidoni; G. Sanna
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 394 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The enrichment factor of carbon-13 m the products of multiphoton dissociation of CzFsCl has been investigated asa function of CO&xer wavelength and fluence. Pressure effects have been studied both on the pure sample and in the presence of several additives (He, Xe, 02. Hz. NO, 12). Dissociation of 12C2FsCl and enrichment in carbon-13 are strongly affected by 02, which reacts with the fluoroalkyl radicals formed in the dissociation process.
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