Isomeric Mono- and Bis[(phosphane)gold(I)] Thiocyanate Complexes
✍ Scribed by Raphael J. F. Berger; Michael Patzschke; Daniel Schneider; Hubert Schmidbaur; Dage Sundholm
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 326 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
Gold(I) / Gold(II) / Diphenyl(trimethylsilylmethyl)phosphane / Ligand effects The reaction of diphenyl(trimethylsilylmethyl)phosphane CH 2 SiMe 3 )(PPh 3 )](CF 3 SO 3 ) (4), the latter mixed with the symmetrical derivatives [Au(PPh 2 R) 2 ](CF 3 SO 3 ) (R = Ph, CH 2 -with [AuCl(tht)] affords the gol
## Abstract The reactions of the tetraphosphane donor ligand (Ph~2~PCH~2~)~2~NCH~2~CH~2~N(CH~2~PPh~2~)~2~ with the gold precursors [AuCl(tht)] or [Au(C~6~F~5~)(tht)] (tht = tetrahydrothiophene) leads to complexes [Au~4~R~4~{(Ph~2~PCH~2~)~2~NCH~2~CH~2~N(CH~2~PPh~2~)~2~}] [R = Cl (1) or C~6~F~5~ (2)]
## Abstract Water‐soluble gold(I) and palladium(II) complexes containing different thiolates and the phosphanes 1,3,5‐triaza‐7‐phosphaadamantane (PTA) and 3,7‐diacetyl‐1,3,7‐triaza‐5‐phosphabicyclo[3.3.1]nonane (DAPTA) are described. The complexes were characterised by spectroscopic techniques incl