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(Triphenylphosphane)gold(I) Scrambling in a Hexanuclear Complex of Phenylene-1,2-bis(phosphane)

✍ Scribed by Assmann, Bernd ;Schmidbaur, Hubert


Publisher
Wiley (John Wiley & Sons)
Year
1997
Tongue
English
Weight
226 KB
Volume
130
Category
Article
ISSN
0009-2940

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Covalently Bonded Bis(phosphane)gold(I)
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## Abstract The unexpected finding that the complex [Au(PPh~3~)~2~]PF~6~ (C1) catalyses the specific hydration of 1‐octyne, (__p__‐phenoxyphenyl)acetylene, phenylacetylene, (__p__‐chlorophenyl)acetylene and benzylacetylene at 100 °C in the presence of H~2~SO~4~ and THF or methanol as solvents, spec