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Gold(I) and Palladium(II) Thiolato Complexes Containing Water-Soluble Phosphane Ligands

✍ Scribed by Elena Vergara; Susana Miranda; Fabian Mohr; Elena Cerrada; Edward R. T. Tiekink; Pilar Romero; Aránzazu Mendía; Mariano Laguna

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
197 KB
Volume
2007
Category
Article
ISSN
1434-1948

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✦ Synopsis

Abstract

Water‐soluble gold(I) and palladium(II) complexes containing different thiolates and the phosphanes 1,3,5‐triaza‐7‐phosphaadamantane (PTA) and 3,7‐diacetyl‐1,3,7‐triaza‐5‐phosphabicyclo[3.3.1]nonane (DAPTA) are described. The complexes were characterised by spectroscopic techniques including 2D NMR experiments, and the complexes [Au(S~2~CNEt~2~)(PTA)], trans‐[Pd(SC~5~H~4~N)~2~(PTA)~2~] and trans‐[Pd(SC~5~H~4~N)~2~(DAPTA)~2~] were additionally characterised by X‐ray crystallography; the latter complex is one of the few structurally characterised DAPTA complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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