IR-laser induced interconversions of hydrogen-bonded dimers in cryogenic matrices
β Scribed by O. Schrems
- Book ID
- 107802772
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 313 KB
- Volume
- 141
- Category
- Article
- ISSN
- 0022-2860
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Sharp peaks were observed in the IR spectra of ally1 alcohol dimers in the "OH and TOH regions in low-temperature Ar and N2 matrices. In Ar 3 peak nt 3587 cm-' was found to increase in intensity upon annealing and dccresse upon IR irradistion;it is concluded that this peak is due to an OH..a interac
Cryogemc malrlces conlammg molecular aggregalcs of methyl mlrlle or mclhanol have been unduled w11h a cwCO2 laser. Al lhc irradwtmn frequency hole burnmg was observed by means of B gratmg Infrared speclrophofomeler. The resullc suggest that vlbrallonal absorpllon bncshapes of aggrcgatcs m cryogcnlc