Ketenimines are important functional groups that show enhanced reactivity in nucleophilic addition and cycloaddition reactions. Furthermore, compounds containing this moiety are useful starting materials which have been applied in heterocycle chemistry. [1] We recently reported the synthesis of the
✦ LIBER ✦
Hydrogen-Bonded Cyclic Dimer Formation in Temperature-Induced Reversal of Tautomerism of Salicylideneanilines
✍ Scribed by Fujiwara, Toshikatsu; Harada, Jun; Ogawa, Keiichiro
- Book ID
- 117997801
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 875 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
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## Abstract A triple hydrogen‐bonding module based on 6‐alkynyl‐2‐amino‐3__H__‐pyrimidin‐4‐one was developed such as for self‐dimerization and for nucleobase recognition processes. The strength of the module for the self‐dimerization was determined by NMR and fluorimetric analyses in chloroform (Δ_