Thermodynamics of hydrogen-bonded complex formation in chloroform + cyclic ether mixtures
β Scribed by Americo Inglese
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 838 KB
- Volume
- 199
- Category
- Article
- ISSN
- 0040-6031
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π SIMILAR VOLUMES
Molecular dynamics simulations of charged and neutral solutes in dimethyl sulfoxide (DMSO)-chloroform mixtures reveal pronounced nonideality in the solute diffusion with changes of composition of the mixtures. The diffusion coefficient of the anionic solute first decreases, passes through a minimum
The validity of using the Belles-Drago technique to calculate thermodynamic functions for the hydrogen bonding interactions of an acid with a pair of bases was tested by computer. Sets of 'data' were calculated for five cases having different enthalpies and free energies of association and these 'da