✦ LIBER ✦

Thermodynamics of hydrogen bonding in coal-derived liquids. Failure of the Bolles-Drago approach applied to mixtures

✍ Scribed by Orville R. Weyrich Jr.; John W. Larsen

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 220 KB
Volume: 62
Category: Article
ISSN: 0016-2361
DOI: 10.1016/0016-2361(83)90175-8

No coin nor oath required. For personal study only.

✦ Synopsis

The validity of using the Belles-Drago technique to calculate thermodynamic functions for the hydrogen bonding interactions of an acid with a pair of bases was tested by computer. Sets of 'data' were calculated for five cases having different enthalpies and free energies of association and these 'data' were used in the Belles-Drago treatment to recalculate the thermodynamic perameters. If the enthalpies and free energies of association of the acid with the two bases are different, the Belles-Drago treatment fails.

📜 SIMILAR VOLUMES

Heats of interaction between coal-liquid

Heats of interaction between coal-liquid fractions and acids or bases. application of the bolles—drago approach to mixtures

✍ K.C. Tewari; P. Stein; N.C. Li 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 205 KB

In summary, these results clearly demonstrate the value of cross-polarization n.m.r. methods in studies of coal-solvent interactions. They show that sorbed solvent molecules in coal-solvent systems retain a degree of molecular freedom, which is great enough to remove chemical shift anisotropy but in