IR hole burning by cw CO2 laser irradiation of molecular aggregates in cryogenic matrices

✍ Scribed by Peter Felder; Hs.H. Günthard

• Publisher: Elsevier Science
• Year: 1982
• Tongue: English
• Weight: 320 KB
• Volume: 88
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(82)83156-4

✦ Synopsis

Cryogemc malrlces conlammg molecular aggregalcs of methyl mlrlle or mclhanol have been unduled w11h a cwCO2 laser. Al lhc irradwtmn frequency hole burnmg was observed by means of B gratmg Infrared speclrophofomeler. The resullc suggest that vlbrallonal absorpllon bncshapes of aggrcgatcs m cryogcnlc matrices arc dommalcd by mhomogcncous hnc-brmdcnm&!. Infrared laser-induced processes in mat&~-isolated species have received considerable attention in tile last