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IR studies of hydrogen bonded complexes formed by CH donors in cryogenic solutions

✍ Scribed by K.G. Tokhadze; N.A. Tkhorzhevskaya

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
653 KB
Volume
32
Category
Article
ISSN
0167-7322

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Polyethylene (PE) fdm is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp%(CO)z (Cp%$-CsMes) using supercritical CO, and subsequently saturated with HORe (RF= (CFs)zCH or (CFs)sC). At 200 K, the equilibrium between Cp\*Ir(CO)z and the