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Interconversion and Reactivity of Two Heterometallic Tin-Containing Cuboidal Clusters from [Mo 3 S 4 (H 2 O) 9 ] 4+ : X-ray Structure of the Single Cube with an Mo 3 SnS 4 Core

✍ Scribed by Varey, Jane E.; Lamprecht, Gert J.; Fedin, Vladimir P.; Holder, Alvin; Clegg, William; Elsegood, Mark R. J.; Sykes, A. Geoffrey

Book ID: 127286209
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 195 KB
Volume: 35
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic951659m

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ChemInform Abstract: Interconversion and

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Interconversion and Reactivity of Two Heterometallic Tin-Containing Cuboidal Clusters from (Mo3S4(H2O)9)4+: X-Ray Structure of the Single Cube with an Mo3SnS4 Core. -The solution chemistry of the single and double cuboidal clusters ( Mo3SnS4(H2O)12)6+ and (Mo6SnS8(H2O)18)8+ is studied and the struc

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ChemInform Abstract: Heterometallic Cuboidal Complexes as Derivatives of (Mo3S4(H2O)9)4+. Interconversion of Single and Double Cubes and Related Studies

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4 (NCS) 9 ] •0.5H 2 O (space group C2/c, monoclinic, Z = 8) and for [Mo 6 SnSe 8 (H 2 O) 18 ] (TosO -) 8 •2TosOH•28H 2 O (space group P1, triclinic, Z = 1). The latter one is the first example of an Se-containing corner-shared double cube. Conversion of single cubes into corner-shared double cubes i

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ChemInform Abstract: Preparation, Structure, and Reactivity of Ge-Containing Heterometallic Cube Derivatives of [M3E4(H2O)9]4+ (M: Mo, W; E: S, Se).

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