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Preparation, Structure, and Reactivity of Ge-Containing Heterometallic Cube Derivatives of [M 3 E 4 (H 2 O) 9 ] 4+ (M = Mo, W; E = S, Se)

✍ Scribed by Seo, Mi-Sook; Fedin, Vladimir P.; Sokolov, Maxim N.; Hernandez-Molina, Rita; Sokolowski, Achim; Elsegood, Mark R. J.; Clegg, William; Sykes, A. Geoffrey

Book ID
126021566
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
114 KB
Volume
40
Category
Article
ISSN
0020-1669

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4 (NCS) 9 ] β€’0.5H 2 O (space group C2/c, monoclinic, Z = 8) and for [Mo 6 SnSe 8 (H 2 O) 18 ] (TosO -) 8 β€’2TosOHβ€’28H 2 O (space group P1, triclinic, Z = 1). The latter one is the first example of an Se-containing corner-shared double cube. Conversion of single cubes into corner-shared double cubes i