4 (NCS) 9 ] β’0.5H 2 O (space group C2/c, monoclinic, Z = 8) and for [Mo 6 SnSe 8 (H 2 O) 18 ] (TosO -) 8 β’2TosOHβ’28H 2 O (space group P1, triclinic, Z = 1). The latter one is the first example of an Se-containing corner-shared double cube. Conversion of single cubes into corner-shared double cubes i
ChemInform Abstract: Preparation, Structure, and Reactivity of Ge-Containing Heterometallic Cube Derivatives of [M3E4(H2O)9]4+ (M: Mo, W; E: S, Se).
β Scribed by Mi-Sook Seo; Vladimir P. Fedin; Maxim N. Sokolov; Rita Hernandez-Molina; Achim Sokolowski; Mark R. J. Elsegood; William Clegg; A. Geoffrey Sykes
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Interconversion and Reactivity of Two Heterometallic Tin-Containing Cuboidal Clusters from (Mo3S4(H2O)9)4+: X-Ray Structure of the Single Cube with an Mo3SnS4 Core. -The solution chemistry of the single and double cuboidal clusters ( Mo3SnS4(H2O)12)6+ and (Mo6SnS8(H2O)18)8+ is studied and the struc