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ChemInform Abstract: Interconversion and Reactivity of Two Heterometallic Tin-Containing Cuboidal Clusters from (Mo3S4(H2O)9)4+: X-Ray Structure of the Single Cube with an Mo3SnS4 Core.

✍ Scribed by J. E. VAREY; G. J. LAMPRECHT; V. P. FEDIN; A. HOLDER; W. CLEGG; M. R. J. ELSEGOOD; A. G. SYKES

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Interconversion and Reactivity of Two Heterometallic Tin-Containing Cuboidal Clusters from (Mo3S4(H2O)9)4+: X-Ray Structure of the Single Cube with an Mo3SnS4 Core.

-The solution chemistry of the single and double cuboidal clusters ( Mo3SnS4(H2O)12)6+ and (Mo6SnS8(H2O)18)8+ is studied and the structure of the dimethylammonium salt of (Mo3(SnCl3)S4(NCS)9)6-(IV) is determined by single crystal XRD (space group C2/c, Z = 8). The tin atom of the single cube has a high affinity for Cl-. In the case of the double cube, Cl-initiates the decomposition to the single cube and the cuboidal cation of (II). High-yield redox-induced interconversions of the single and double cubes are achieved. -(VAREY,

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