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Injection induced charging of HfO2 insulators on Si

✍ Scribed by V.V Afanas’ev; A Stesmans


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
97 KB
Volume
109
Category
Article
ISSN
0921-5107

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✦ Synopsis


Charge trapping in HfO 2 films on Si(1 0 0) was studied using generation of electron-hole pairs in the oxide by 10 eV photons. The oxide deposition chemistry strongly influences the density and sign of the trapped charge: positive charge is observed in films obtained from HfCl 4 and metallo-organics, while negative charge is dominant in the films grown from Hf(NO 3 ) 4 . The weak dependence of the trapped charge on the HfO 2 thickness suggests that charging is associated with a silicon oxide interlayer grown between the Si and HfO 2 during deposition. The latter is affirmed by enhancement of the charging after oxidation of the samples at 650 • C, indicating the interfacial silicon oxide as being the key factor determining the electrical stability of the HfO 2 insulating stacks.


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