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Inhibition of sterol biosynthesis by 9α-fluoro and 9α-hydroxy derivatives of 5α-cholest-8(14)-en-3β-ol-15-one

✍ Scribed by George J. Schroepfer Jr.; Edward J. Parish; Mitsuhiru Tsuda; Andrew A. Kandutsch

Book ID
118313732
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
451 KB
Volume
91
Category
Article
ISSN
0006-291X

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Sterol synthesis. Synthesis of 15-oxygen
Sterol synthesis. Synthesis of 15-oxygenated 5α, 14β-cholest-7-en-3β-ol derivatives
✍ Edward J. Parish; George J. Schroepfer Jr. 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 918 KB

Treatment of 3~.benzoyloxy-140, 15wepoxy-5(~.cholesg-7-ene with boron trifluoride-etherate 8ave, in 43% yield, 30-benzoyloxy-Sa, 14~cholest-7-en,15-one with the unnatt~ral C-D ring juncture, Reduction of the latteg compound with lithium aluminum hydride gave 15a, 14O-~holest-7.en'3p, 15wdiol and 5~,