Influence of cross-correlation between dipolar and chemical shift anisotropy relaxation mechanisms upon the transverse relaxation rates of 15N in macromolecules
β Scribed by Jonathan Boyd; Ulrich Hommel; V.V. Krishnan
- Book ID
- 107735297
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 574 KB
- Volume
- 187
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
We present a simple method for extracting interference effects between chemical shift anisotropy (CSA) and dipolar coupling from spin relaxation measurements in macromolecules, and we apply this method to extracting cross-correlation rates involving interference of amide 15N CSA and 15N-1H dipolar c
## Abstract We describe direct methods for the measurement of the transverse and longitudinal ^15^N chemical shift anisotropyβdipolar crossβcorrelation rates based on comparison of the ^15^N doublet components observed in ^1^Hβcoupled ^1^Hβ^15^N HSQCβtype spectra. This allows the determination of t
The cross-correlation spectral density of chemical shift anisotropy and dipolar interactions in isotropic solution of methyl formate is measured using a novel NMR technique designed to monitor the appearance of longitudinal two-spin order 2I,S, during mversion recovery. The result is tentatively int