Influence of cross-correlation between dipolar and anisotropic chemical shift relaxation mechanisms upon longitudinal relaxation rates of 15N in macromolecules
โ Scribed by Jonathan Boyd; Ulrich Hommel; Iain D. Campbell
- Book ID
- 107734847
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 504 KB
- Volume
- 175
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
We present a simple method for extracting interference effects between chemical shift anisotropy (CSA) and dipolar coupling from spin relaxation measurements in macromolecules, and we apply this method to extracting cross-correlation rates involving interference of amide 15N CSA and 15N-1H dipolar c
## Abstract We describe direct methods for the measurement of the transverse and longitudinal ^15^N chemical shift anisotropyโdipolar crossโcorrelation rates based on comparison of the ^15^N doublet components observed in ^1^Hโcoupled ^1^Hโ^15^N HSQCโtype spectra. This allows the determination of t