✦ LIBER ✦

Observation of 2izsz order in NMR relaxation studies for measuring cross-correlation of chemical shift anisotropy and dipolar interactions

✍ Scribed by Guy Jaccard; Stephen Wimperis; Geoffrey Bodenhausen

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 502 KB
Volume: 138
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80133-1

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✦ Synopsis

The cross-correlation spectral density of chemical shift anisotropy and dipolar interactions in isotropic solution of methyl formate is measured using a novel NMR technique designed to monitor the appearance of longitudinal two-spin order 2I,S, during mversion recovery. The result is tentatively interpreted in terms of the orientation of the '%-'H internuclear vector with respect to the principal axes of the "C chemical shift anisotropy tensor of the carboxyl group.

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