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Implications of the large carbon kinetic isotope effect in the reaction CH 4 + Cl for the 13 C/ 12 C ratio of stratospheric CH 4

✍ Scribed by Bergamaschi, P.; Brühl, C.; Brenninkmeijer, C. A. M.; Saueressig, G.; Crowley, J. N.; Grooß, J. U.; Fischer, H.; Crutzen, P. J.

Book ID
118668574
Publisher
American Geophysical Union
Year
1996
Tongue
English
Weight
494 KB
Volume
23
Category
Article
ISSN
1944-8007

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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 ± 2 K and 1013 ± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~