The 13C and D kinetic isotope effects in
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Karen L. Feilberg; David W. T. Griffith; Matthew S. Johnson; Claus J. Nielsen
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Article
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2004
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John Wiley and Sons
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English
β 134 KB
π 1 views
## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 Β± 2 K and 1013 Β± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~