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Imaging the isotope effects in the ground state reaction of Cl CH4 and CD4

โœ Scribed by Zhou, J.; Zhang, B.; Lin, J. J.; Liu, K.

Book ID
126625427
Publisher
Taylor and Francis Group
Year
2005
Tongue
English
Weight
660 KB
Volume
103
Category
Article
ISSN
0026-8976

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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 ยฑ 2 K and 1013 ยฑ 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~