Carbon kinetic isotope effect in the reaction of CH 4 with Cl atoms
β Scribed by Saueressig, G.; Bergamaschi, P.; Crowley, J. N.; Fischer, H.; Harris, G. W.
- Book ID
- 119692801
- Publisher
- American Geophysical Union
- Year
- 1995
- Tongue
- English
- Weight
- 290 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1944-8007
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Recent studies suggest that the destruction of methane by Cl\* in the marine boundary layer could be accounted for as another major sink besides the methane destruction by OH l . High level ab initio molecular orbital calculations have been carried out to study the CH4 + Cl l reaction, the carbon Ki
The competitive reactions of Br atoms with CH, and CD, were studied over the temperature range of 562' to 637Β°K. Over this temperature interval, the kinetic isotope effect, k,/k,, varied from 3.05 to 2.47 for the reactions Br + CH, -% HBr + CH, The rate constant ratio k,/k, , expressed in Arrhenius