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Study of the Carbon-13 and Deuterium Kinetic Isotope Effects in the Cl and OH Reactions of CH 4 and CH 3 Cl

✍ Scribed by Sellevåg, Stig R.; Nyman, Gunnar; Nielsen, Claus J.


Book ID
120492898
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
210 KB
Volume
110
Category
Article
ISSN
1089-5639

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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 ± 2 K and 1013 ± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~