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Experimental and Theoretical Study of the Carbon-13 and Deuterium Kinetic Isotope Effects in the Cl and OH Reactions of CH 3 F

✍ Scribed by Marinkovic, Marina; Gruber-Stadler, Margret; Nicovich, J. Michael; Soller, Raenell; Mülhäuser, Max; Wine, Paul H.; Bache-Andreassen, Lihn; Nielsen, Claus J.

Book ID
120494169
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
497 KB
Volume
112
Category
Article
ISSN
1089-5639

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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 ± 2 K and 1013 ± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~