Laser Bash photolysis of DNOs/RSR'/R"H/Nr mixtures (R&HI, R'=CH, or C,H,, R"=n-hexyl or cyclohexyl) has been coupled with HDO detection by time-resolved tunable diode laser absorption spectroscopy to directly investigate the importance of C-H bond cleavage as the q-independent pathway for the atmosp
Product Branching Fractions and Kinetic Isotope Effects for the Reactions of OH and OD Radicals with CH 3 SH and CH 3 SD
β Scribed by Butkovskaya, N. I.; Setser, D. W.
- Book ID
- 126310196
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 154 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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Laser flash photolysis of D,O,/RCH,/N, and CI,CO/RCH,/N, mixtures (R = CH,S or H) was coupled with CH, detection by time-resolved tunable-diode laser absorption spectroscopy to investigate the importance of C-S bond cleavage as an O,-independent reaction pathway for the atmospherically interesting r
## Abstract A dualβlevel direct dynamic method is employed to study the reaction mechanisms of CF~3~CH~2~OCHF~2~ (HFEβ245fa2; HFEβ245mf) with the OH radicals and Cl atoms. Two hydrogen abstraction channels and two displacement processes are found for each reaction. For further study, the reaction m