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Highly Efficient Iridium Catalyst for Asymmetric Transfer Hydrogenation of Aromatic Ketones under Base-Free Conditions

โœ Scribed by Dong, Zhen-Rong; Li, Yan-Yun; Chen, Jian-Shan; Li, Bao-Zhu; Xing, Yan; Gao, Jing-Xing


Book ID
126918360
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
59 KB
Volume
7
Category
Article
ISSN
1523-7060

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Highly efficient catalysts derived from
โœ Du Xiang-Dong; Dai Li-Xin; Hou Xue-Long; Xia Li-Jun; Tang Ming-Hua ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 207 KB ๐Ÿ‘ 1 views

Planar chiral ferrocenes 1 and its diastereoisomer 2 were found to be good ligands for. the ruthenium catalyzed asymmetric transfer hydrogenation of ketones with i-PrOH as hydrogen source under refluxing in the presence of sodium hydroxide. The results showed that the absolute configuration of alcoh