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Highly Efficient Chiral PNNP Ligand for Asymmetric Transfer Hydrogenation of Aromatic Ketones in Water.

โœ Scribed by Yan Xing; Jian-Shan Chen; Zhen-Rong Dong; Yan-Yun Li; Jing-Xing Gao


Publisher
John Wiley and Sons
Year
2006
Weight
21 KB
Volume
37
Category
Article
ISSN
0931-7597

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Planar chiral ferrocenes 1 and its diastereoisomer 2 were found to be good ligands for. the ruthenium catalyzed asymmetric transfer hydrogenation of ketones with i-PrOH as hydrogen source under refluxing in the presence of sodium hydroxide. The results showed that the absolute configuration of alcoh