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Highly Efficient Iridium Catalyst for Asymmetric Transfer Hydrogenation of Aromatic Ketones under Base-Free Conditions.

✍ Scribed by Zhen-Rong Dong; Yan-Yun Li; Jian-Shan Chen; Bao-Zhu Li; Yan Xing; Jing-Xing Gao

Publisher: John Wiley and Sons
Year: 2005
Weight: 25 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200533028

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Planar chiral ferrocenes 1 and its diastereoisomer 2 were found to be good ligands for. the ruthenium catalyzed asymmetric transfer hydrogenation of ketones with i-PrOH as hydrogen source under refluxing in the presence of sodium hydroxide. The results showed that the absolute configuration of alcoh