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Accelerated Asymmetric Transfer Hydrogenation of Aromatic Ketones in Water.

✍ Scribed by Xiaofeng Wu; Xiaoguang Li; William Hems; Frank King; Jianliang Xiao


Publisher
John Wiley and Sons
Year
2004
Weight
25 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract A new polyethylene glycol‐supported chiral monosulfonamide was synthesized from (__R__,__R__)‐1,2‐diaminocyclohexane and shown to act as a ligand for ruthenium(II)‐catalyzed asymmetric transfer hydrogenation of aromatic ketones in neat water using sodium formate as the hydrogen source.