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Insight into and Practical Application of pH-Controlled Asymmetric Transfer Hydrogenation of Aromatic Ketones in Water

✍ Scribed by Xiaofeng Wu; Xiaoguang Li; Frank King; Jianliang Xiao

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 394 KB
Volume: 44
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200500023

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## Abstract A new polyethylene glycol‐supported chiral monosulfonamide was synthesized from (__R__,__R__)‐1,2‐diaminocyclohexane and shown to act as a ligand for ruthenium(II)‐catalyzed asymmetric transfer hydrogenation of aromatic ketones in neat water using sodium formate as the hydrogen source.