Heterotricyclodecane XV. Synthese von 2,6-Diaza-adamantanen
✍ Scribed by Robert Ernst Portmann; Camille Ganter
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- German
- Weight
- 391 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The synthesis of several derivatives of 2,6‐diaza‐adamantane (2, 3, 5–9) is described using the diepoxides 1 and 4 as starting materials.
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## Abstract Die β‐Benzylaminoketone **1a** — **e** wurden mittels der Mannich‐Reaktion synthetisiert und daraus die __anti__‐Amino‐oxime **2a** — **e** hergestellt. Die Umsetzung mit Aldehyden führt zu 1,2,5,6‐Tetrahydropyrimidin‐3‐oxiden **3a** — **h**. Durch Cycloaddition mit Acetylendicarbonsäur