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Gas-phase reaction of phenyl cation with diethylamine

✍ Scribed by T. A. Kochina; D. V. Vrazhnov; I. S. Ignatyev; E. O. Kalinin; E. N. Sinotova


Book ID
110395972
Publisher
Springer
Year
2002
Tongue
English
Weight
52 KB
Volume
253
Category
Article
ISSN
1588-2780

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In the gas phase, the (CH,),SiOSi(CH,),' and (CH,),Si'OSi(CH,)CH, ions were formed in the external source of a FT-ICR mass spectrometer by fragmentation of (CH,),SiOSi(CH,),". In the cell, the electrophilic center of these ions reacts with water to give product-ions which undergo, spontaneously or