Ion-Molecule Reactions of Free Phenyl Cations with Diethylamine in the Gas Phase: Radiochemical Study
β Scribed by T. A. Kochina; E. O. Kalinin; E. N. Sinotova; I. S. Ignat'ev; A. A. Kinebas
- Book ID
- 110312047
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 42 KB
- Volume
- 71
- Category
- Article
- ISSN
- 1070-3632
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## Mass -selected Ti+ or TiCl; ions can be used to activate pyridine molecules. This unusual chemical activation is evident from reaction product tandem (MS/MS or MS? spectra recorded at nominal zero collision energy which display abundant ions due to dehydrogenation and HCN loss from the ionholec
The gas-phase ion-molecule reactions of the phosphonium ion formed by electron impact with OP(OCH 3 ) 2 ' neutral trimethyl phosphite were studied with the use of a quadrupole ion trap (QIT) mass spectrometer. Observed reactions include competing methoxy transfers between and the neutral species to