Reaction of the Butadiene Cation with Ethylene in the Gas Phase
โ Scribed by Hu, Haiqing; Wenthold, Paul G.
- Book ID
- 127049550
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 57 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
In the gas phase, (CH 3 ) 3 SiOSi Y (CH 3 ) 2 and (CH 3 )CH 2 SiOSi Y (CH 3 ) 2 ions 1 and 2 were formed in the external source of a Fourier transform ion cyclofrom resonance (FT-ICR) spectrometer by electron impact ionization of (CH 3 ) 3 SiOSi(CH 3 ) 3 . In the FT-ICR cell, the electrophilic cente
The gas-phase kinetics of the reaction between Cuz and C2H4 have been studied as a function of pressure in a fast-flow reactor. The limiting low-pressure, third-order rate constant for the reaction was found to be (9.3 + I .4) x 1 Oew cm6 s-' in He. Modeling studies of this rate constant imply that