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Reaction of the copper dimer, Cu2 with ethylene in the gas phase

✍ Scribed by Li Lian; Farah Akhtar; Peter A. Hackett; David M. Rayner

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
461 KB
Volume
205
Category
Article
ISSN
0009-2614

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✦ Synopsis

The gas-phase kinetics of the reaction between Cuz and C2H4 have been studied as a function of pressure in a fast-flow reactor.

The limiting low-pressure, third-order rate constant for the reaction was found to be (9.3 + I .4) x 1 Oew cm6 s-' in He. Modeling studies of this rate constant imply that Cu2(C2H4) is bound by at least 20 kcal mol-'.

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