Iminoquinone coordination to copper(I) in the [Cu(PhenoxBQ)(μ-Cl)]2 dimer
✍ Scribed by Gabor Speier; Jozsef Csihony; Anne M. Whalen; Cortlandt G. Pierpont
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 559 KB
- Volume
- 245
- Category
- Article
- ISSN
- 0020-1693
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## Abstract Novel copper(I) mixed‐ligand complexes containing 1,2‐bis(diphenylphosphanyl)benzene (dppbz) and 2,4‐dithiouracil (2,4‐dtucH~2~) ligands have been synthesised by addition of the thione ligand to the dinuclear [Cu(μ‐X)(dppbz)]~2~ intermediate in acetonitrile/methanol or acetone solution.
The architecture of the tetrapodal pentaamine ligand 2,6-applicable), and X-ray structure determination. While the solid state structures show varying degrees of distortion of bis(1Ј,3Ј-diamino-2Ј-methylprop-2Ј-yl)pyridine (pyN 4 , 1) allows it to coordinate to nickel(II) as a square pyramidal the l