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Synthesis, Crystal Structures, and Properties of the Copper(I) Halide Coordination Polymers 2[CuX(μ-2-chloropyrazine-N, N')] (X = Cl, Br), 1[CuI(2-chloropyrazine-N)], and [Cu2I2(2-chloropyrazine)]

✍ Scribed by Christian Näther; Mario Wriedt; Inke Jeß


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
461 KB
Volume
628
Category
Article
ISSN
0372-7874

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✍ Sudipta Dalai; Partha Sarathi Mukherjee; Guillaume Rogez; Talal Mallah; Michael  📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 164 KB 👁 1 views

Two new polynuclear complexes of Cu II , [Cu 2 (fum)(µ-OH)(bpy) 2 (H 2 O)](NO 3 )•2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]•2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.