Gas-Phase Reactions of Dicoordinated Boron Cations with Alcohols
β Scribed by Ranatunga, Thilini D.; Kenttaemaa, Hilkka I.
- Book ID
- 126215691
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 843 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
As a result of an extensive delocalization of charge and a unique covalent structure, the cation has, in CH 3 OCH 2 ' e β ect, the character of an ambident electrophile. This cation can, on the one hand, be considered to be a classical electrophile. On the other hand, it may be considered to be a fac
In the gas phase, the (CH,),SiOSi(CH,),' and (CH,),Si'OSi(CH,)CH, ions were formed in the external source of a FT-ICR mass spectrometer by fragmentation of (CH,),SiOSi(CH,),". In the cell, the electrophilic center of these ions reacts with water to give product-ions which undergo, spontaneously or