Free Radical Polymerization of Volume Expandable Vinylcyclopropane
โ Scribed by Sugiyama, Junichi; Ohashi, Keiko; Ueda, Mitsuru
- Book ID
- 127394683
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 434 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0024-9297
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๐ SIMILAR VOLUMES
Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polym
## Abstract New 1,1โdisubstituted 2โvinylcyclopropanes were synthesized by reaction of the corresponding malonyl diesters with __trans__โ1,4โdibromoโ2โbutene and of sodium hydride. The structure of the 2โvinylcyclopropanes could be confirmed by elemental analysis, IR, ^1^H NMR and ^13^C NMR spectro