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Polymerization of cyclic monomers 9. Synthesis and radical polymerization of spirocyclic 2-vinylcyclopropanes

✍ Scribed by Norbert Moszner; Frank Zeuner; Jörg Angermann; Volker Rheinberger

Publisher
Springer
Year
1999
Tongue
English
Weight
182 KB
Volume
43
Category
Article
ISSN
0170-0839

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📜 SIMILAR VOLUMES

Polymerization of cyclic monomers, 2. Sy
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## Abstract New 1,1‐disubstituted 2‐vinylcyclopropanes were synthesized by reaction of the corresponding malonyl diesters with __trans__‐1,4‐dibromo‐2‐butene and of sodium hydride. The structure of the 2‐vinylcyclopropanes could be confirmed by elemental analysis, IR, ^1^H NMR and ^13^C NMR spectro

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## Abstract Multifunctional 2‐vinylcyclopropanes were synthesized by esterification of the 1‐methoxycarbonyl‐2‐vinylcyclopropane‐1‐carboxylic acid with ethylene glycol, 1,1,1‐trimethylolpropane or 1,4‐cyclohexanediol in the presence of 1,3‐dicyclohexylcarbodiimide (DCC). The structure of the new vi

Polymerization of cyclic monomers. VII.
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1,3-Bis[(1-alkoxycarbonyl-2-vinylcyclopropane-1-yl)carboxy]benzenes 1 [RO: CH 3 O (a), C 2 H 5 O (b)] were synthesized by the esterification of the corresponding 1-alkoxycarbonyl-2-vinylcyclopropane-1-carboxylic acids with resorcinol. The structure of the new vinylcyclopropanes was confirmed by elem

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## Abstract New bicyclic 2‐methylene‐1,3‐dioxepanes, were synthesized starting from 2‐bromomethyl‐5,6‐dihydroxy‐1,3‐dioxepanes. The structure of the 2‐methylene‐1,3‐dioxepanes was confirmed by elemental analysis, IR, ^1^H NMR and ^13^C NMR spectroscopy. Radical polymerization of 2‐methylene‐1,3‐dio