Free-radical functionalisation of vinylcyclopropanes
โ Scribed by Olivier Andrey; Boris Camuzat-Dedenis; Laurent Chabaud; Karine Julienne; Yannick Landais; Liliana Parra-Rapado; Philippe Renaud
- Book ID
- 108282380
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 203 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polym
Treatment of vinylcyclopropanes with CO in the presence of BusSnH and AIBN (catalytic) leads to a stannylformylated product via a cyclopropylcarbinyl radical opening to a homoallylie radical.