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Radical ring-opening emulsion polymerization of vinylcyclopropanes

✍ Scribed by Fumio Sanda; Yasushi Takamatsu; Futoshi Hoshino; Takeshi Endo

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 158 KB
Volume: 68
Category: Article
ISSN: 0021-8995
DOI: 10.1002/(sici)1097-4628(19980418)68:3<497::aid-app15>3.0.co;2-s

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✦ Synopsis

Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polymer emulsions were obtained in a spherical shape with single particle size distribution. Meanwhile, emulsion polymerization of CVCP proceeded in only a low conversion.

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