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Free-Radical Functionalization of Vinylcyclopropanes.

✍ Scribed by Olivier Andrey; Boris Camuzat-Dedenis; Laurent Chabaud; Karine Julienne; Yannick Landais; Liliana Parra-Rapado; Philippe Renaud

Book ID: 101956217
Publisher: John Wiley and Sons
Year: 2004
Weight: 241 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200407054

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Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polym